PALLADIUM-CATALYZED RING-CLOSURE TO A NAPHTHOFURANONEACETIC ESTER BY SELECTIVE CARBONYLATION OF DIACETYLENIC PRECURSORS

被引：12

作者：

COSTA, M ^{[1
]}

SANTOS, LD ^{[1
]}

CHIUSOLI, GP ^{[1
]}

GABRIELE, B ^{[1
]}

SALERNO, G ^{[1
]}

机构：

[1] UNIV CALABRIA,DIPARTIMENTO CHIM,I-87100 ARCAVACATA,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 78卷 / 02期

关键词：

D O I：

10.1016/0304-5102(93)85034-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The new naphthofuranoneacetic acid methyl ester IX can be obtained catalyticallY with fair selectivity from the carbonylation of the diacetylenic alcohol I. The use of the soluble complex Pd(thiourea)4I2 leads to a catalytic reaction resulting from the combination of oxidative carbonylation and hydrogenolysis steps in an additive carbonylation.

引用

页码：151 / 158

页数：8

共 9 条

[1] DIYNE RING-CLOSURE INDUCED BY PALLADIUM-CATALYZED CARBONYLATION [J].

CHIUSOLI, GP ;

COSTA, M ;

MASARATI, E ;

SALERNO, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 255 (03) :C35-C38

[2]

CHIUSOLI GP, 1985, GAZZ CHIM ITAL, V115, P691

[3]

CHIUSOLI GP, 1989, SYNTHESIS-STUTTGART, P282

[4] COMPLEXES OF TERPENES WITH TRANSITION METALS .1. REACTIONS OF CIS-OCIMENE AND TRANS-OCIMENE AND OF MYRCENE WITH PALLADIUM(II) [J].

DUNNE, K ;

MCQUILLI.FJ .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1970, (16) :2196-&

[5] COMPLEXES OF TERPENES WITH TRANSITION METALS .2. REACTIONS OF LINALYL AND NEROLIDYL ACETATES, LIMONENE, AND PINENES WITH DISODIUM TETRACHLOROPALLADATE(II) [J].

DUNNE, K ;

MCQUILLI.FJ .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1970, (16) :2200-&

[6] COMPLEXES OF TERPENES WITH TRANSITION METALS .3. DIMERISATION BY MEANS OF TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM [J].

DUNNE, K ;

MCQUILLI.FJ .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1970, (16) :2203-&

[7]

KURNAKOV NS, 1894, J PRACT CHEM, V50, P496

[8] PREPARATION OF MONOLITHIUM ACETYLIDE IN TETRAHYDROFURAN - REACTION WITH ALDEHYDES AND KETONES [J].

MIDLAND, MM .

JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (15) :2250-2252

[9]

MULLER E, 1971, LIEBIGS ANN CHEM, V754, P64

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