VALENCE SHELL MOMENTUM DISTRIBUTIONS, BINDING-ENERGIES, AND CALCULATED WAVEFUNCTION EVALUATION FOR H2S BY BINARY (E,2E) SPECTROSCOPY

被引：15

作者：

COOK, JPD

BRION, CE

HAMNETT, A

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1W5,BC,CANADA

[2] UNIV OXFORD,INORGAN CHEM LAB,OXFORD,ENGLAND

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1979年 / 15卷 / JAN期

关键词：

D O I：

10.1016/0368-2048(79)87037-1

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

We report preliminary results on the binding energy spectrum and molecular orbital momentum distributions of H2S as measured by binary (e,2e) spectroscopy at 400 eV. Extensive final ion state structure associated with ionization from the inner valence molecular orbital of H2S is observed. Three momentum distribution calculations for H2S using basis sets of varying complexity show a better fit than in H2O (J. Electron Spectrosc. 11 (1977) 205) for a given quality of basis set. © 1979.

引用

页码：233 / 236

页数：4

共 10 条

[1] BASIS SET AND ELECTRON CORRELATION EFFECTS ON TOTAL ELECTRON-DENSITY IN H2O, H2S, AND BH
BICERANO, J
MARYNICK, DS
LIPSCOMB, WN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (03) : 732 - 739
[2] COOK JP, UNPUBLISHED
[3] DOMCKE W, J ELECTRON SPECTROSC
[4] GUEST MM, COMMUNICATION
[5] HAMNETT A, 1977, J ELECTRON SPECTRY, V11, P205
[6] MOLECULAR-ORBITAL MOMENTUM DISTRIBUTIONS AND BINDING-ENERGIES FOR H2O USING AN ELECTRON-IMPACT COINCIDENCE SPECTROMETER
HOOD, ST
HAMNETT, A
BRION, CE
[J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1977, 11 (02) : 205 - 224
[7] AN(E,2E) STUDY OF AMMONIA - BINDING-ENERGIES AND MOMENTUM DISTRIBUTIONS OF VALENCE-ELECTRONS
HOOD, ST
HAMNETT, A
BRION, CE
[J]. CHEMICAL PHYSICS LETTERS, 1976, 39 (02) : 252 - 256
[8] McCarthy I. E., 1976, Physics Reports. Physics Letters Section C, V27c, P275, DOI 10.1016/0370-1573(76)90005-3
[9] CALCULATED PHOTOIONIZATION CROSS-SECTIONS AND RELATIVE EXPERIMENTAL PHOTOIONIZATION INTENSITIES FOR A SELECTION OF SMALL MOLECULES
RABALAIS, JW
DEBIES, TP
BERKOSKY, JL
HUANG, JTJ
ELLISON, FO
[J]. JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (02) : 516 - 528
[10] Turner D.W., 1970, MOL PHOTOELECTRON SP

← 1 →