SUGAR ENOLONES .10. NOVEL, HIGHLY STEREOSELECTIVE REARRANGEMENTS OF CHIRAL DIHYDROPYRANONES

被引:11
作者
LICHTENTHALER, FW
NISHIYAMA, S
JARGLIS, P
机构
[1] Institut für Organische Chemie und Biochemie, Technischen Hochschule Darmstadt, D-6100
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 12期
关键词
D O I
10.1002/anie.197909361
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Important chiral synthons have been found in the dihydropyranones of types 1 and 3 derived from sugars. Enediolones 3 can be prepared by new, high‐yield methods. Particular interest attaches to the rearrangement (3)→(2); transfer of chirality takes place from one side of the ring to the other. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany
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页码:936 / 938
页数:3
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