MAGNETIC AND STRUCTURAL-PROPERTIES OF FE IN SINGLE-CRYSTALS OF YBA2CU3-XFEXO7-DELTA

被引：19

作者：

NUNEZ, L ^{[1
]}

ROGERS, RD ^{[1
]}

CRABTREE, GW ^{[1
]}

WELP, U ^{[1
]}

VANDERVOORT, K ^{[1
]}

UMEZAWA, A ^{[1
]}

FANG, Y ^{[1
]}

机构：

[1] ARGONNE NATL LAB, DIV MAT SCI, ARGONNE, IL 60439 USA

来源：

PHYSICAL REVIEW B | 1991年 / 44卷 / 09期

关键词：

D O I：

10.1103/PhysRevB.44.4526

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Magnetization and lattice-constant measurements were done on four single crystals of YBa2Cu(3-x)Fe(x)O7-delta with Fe concentrations of x = 0.06, 0.09, 0.15, and 0.24 to determine the structural and normal-state properties. Measurements of magnetization as a function of temperature were done in a temperature range between 90 and 300 K and analyzed using a Curie-Weiss law with a temperature-independent background. The effective magnetic moment obtained corresponds to a low spin state of Fe3+ with a magnitude of 2.18-mu-B. Magnetic anisotropy between the ab plane and the c direction is only present for the concentration of x = 0.06 and is attributed to the various oxygen environments surrounding the iron. For concentrations larger than x = 0.06, the moment on Fe is isotropic and Curie-Weiss fits predict uniform antiferromagnetic ordering. Structural measurements exhibit an orthorhombic-tetragonal transition at an Fe concentration of x = 0.15, similar to that observed in the polycrystalline material.

引用

页码：4526 / 4531

页数：6

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