COLLISION-INDUCED STATE-TO-STATE ENERGY-TRANSFER IN THE NU(2)+3-NU(3) ROVIBRATIONAL MANIFOLD OF GAS-PHASE ACETYLENE

被引：37

作者：

MILCE, AP

BARTH, HD

ORR, BJ

机构：

[1] School of Chemistry, Macquarie University

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 03期

关键词：

D O I：

10.1063/1.466487

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Time-resolved infrared-ultraviolet double resonance spectroscopy is used to measure collision-induced rovibrational energy transfer in the v(2)+3v(3) region (similar to 11 600 cm(-1)) of gas-phase acetylene. Of particular interest is rotationally resolved V-V transfer between the Fermi-coupled 2(1)3(3) and 1(1)2(3)4(3)5(1) levels, for which the rate is relatively high (approximately 13% of the Lennard-Jones collision rate) and the relevant rovibrational states markedly perturbed.

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页码：2398 / 2401

页数：4

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