REACTIONS OF TRIALKYLMETHYLENEPHOSPHORANES WITH 1,5-CYCLOOCTADIENE-PLATINUM(II) AND IRIDIUM(I) COMPLEXES

被引：13

作者：

BLASCHKE, G

SCHMIDBAUR, H

KASKA, WC

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,D-8046 GARCHING,FED REP GER

[2] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)94390-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of (CH3)3PCH2 and CH3[CH3)3C]2PCH2 with (COD)Pt(CH3)2 result in the formation of the corresponding cis-dimethylplatinum(II)-bis-ylide complexes. With (COD)PtCl2, a transylidation takes place, but the expected chelating ylide complexes cannot be isolated. Treatment of (COD)2Ir2Cl2 with excess CH3(CH3)3C]2PCH2 gives the mononuclear ylide chelate (COD)Ir(CH2)2P(CH3)3]2. © 1979.

引用

页码：251 / 255

页数：5

共 12 条

[1]

[Anonymous], 2007, INORG SYN

[2]

BALDWIN JC, 1979, INORG CHEM, V18, P687

[3] REACTIONS OF(PI-1,5-CYCLOOCTADIENE)ORGANOPLATINUM(II)COMPOUNDS AND SYNTHESIS OF PERFLUOROALKYLPLATINUM COMPLEXES [J].