STEREOSELECTIVE SYNTHESIS OF (+/-)-TRICHODIENE

被引:24
作者
HARDING, KE
CLEMENT, KS
TSENG, CY
机构
[1] Department of Chemistry, Texas A&M University, College Station
关键词
D O I
10.1021/jo00301a036
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Details of a convergent stereoselective synthesis of trichodiene (1) from simple monocyclic starting materials are reported. Stereochemical control is effected by Nazarov cyclization of dienone 14 and C-C bond cleavage of the resulting tricyclic products 15 to form cyano dienes 20. © 1990, American Chemical Society. All rights reserved.
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页码:4403 / 4410
页数:8
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