STEREOSELECTIVE SYNTHESIS OF (+/-)-TRICHODIENE

被引：24

作者：

HARDING, KE

CLEMENT, KS

TSENG, CY

机构：

[1] Department of Chemistry, Texas A&M University, College Station

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 14期

关键词：

D O I：

10.1021/jo00301a036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Details of a convergent stereoselective synthesis of trichodiene (1) from simple monocyclic starting materials are reported. Stereochemical control is effected by Nazarov cyclization of dienone 14 and C-C bond cleavage of the resulting tricyclic products 15 to form cyano dienes 20. © 1990, American Chemical Society. All rights reserved.

引用

页码：4403 / 4410

页数：8

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