SYNTHESIS AND STRUCTURES OF 2 ISOMERS OF [RE3RU(S)(C5H4N)(C5H4NS)2(CO)11] WHICH DIFFER IN THE DISTRIBUTION OF PYRIDINE-2-THIONATO LIGANDS BETWEEN DOUBLY-BRIDGING AND TRIPLY-BRIDGING POSITIONS

被引：29

作者：

DEEMING, AJ ^{[1
]}

KARIM, M ^{[1
]}

POWELL, NI ^{[1
]}

HARDCASTLE, KI ^{[1
]}

机构：

[1] CALIF STATE UNIV NORTHRIDGE,DEPT CHEM,NORTHRIDGE,CA 91330

来源：

POLYHEDRON | 1990年 / 9卷 / 04期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0277-5387(00)86244-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pyridine-2-thionato (pyS) bridged compound [Re2(pyS)2(CO)6] reacts with [Ru3(CO)12] to give various tetranuclear compounds built from Re(pyS)(CO)3 and Ru(CO)x (x = 2, 3 or 4) units: [ReRu3(S)(C5H4N)(CO)14], [Re2Ru2(S)(C5H4N)(pyS)(CO)13], and [Re3Ru(S)(C5H4N)(pyS)2(CO)11] as two isomers. X-ray structures of these isomers show that one contains two doubly-bridging pyS ligands and the other one doubly- and one triply-bridging pyS ligands. © 1990.

引用

页码：623 / 626

页数：4

共 5 条

[1] DI-NUCLEAR AND TRI-NUCLEAR COMPLEXES OF PALLADIUM(II) CONTAINING DOUBLY-BRIDGING AND TRIPLY-BRIDGING PYRIDINE-2-THIONATO (PYS) LIGANDS - CRYSTAL-STRUCTURE OF [PD3(C6H4CH2NME2)3(PYS)2][BF4] [J].

DEEMING, AJ ;

MEAH, MN ;

BATES, PA ;

HURSTHOUSE, MB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (08) :2193-2199

[2] A NEW TYPE OF PYRIDINE-2-THIONATO BRIDGE - X-RAY CRYSTAL-STRUCTURE OF THE COMPLEX [RE2(MEPYS)2(CO)6] WHERE MEPYS IS THE 6-METHYLPYRIDINE-2-THIONATO LIGAND [J].

DEEMING, AJ ;

KARIM, M ;

BATES, PA ;

HURSTHOUSE, MB .

POLYHEDRON, 1988, 7 (15) :1401-1403

[3] [RHPD2(PYS)4(ETA-3-C4H7)2][BF4] - SYNTHESIS AND X-RAY STRUCTURE OF A MIXED-METAL TRINUCLEAR COMPLEX CONTAINING 2 MU-3-PYRIDINE-2-THIONATO (PYS) LIGANDS [J].

DEEMING, AJ ;

MEAH, MN ;

BATES, PA ;

HURSTHOUSE, MB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (01) :235-238

[4]

DEEMING AJ, UNPUB

[5]

ORO LA, 1986, NOUV J CHIM, V10, P75

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