METHYLALUMINOXANE HALOALKANE AS INITIATOR SYSTEM FOR STYRENE POLYMERIZATION

被引：10

作者：

CHIEN, JCW

DONG, SZ

机构：

[1] Department of Polymer Science and Engineering, Materials Research Laboratories, University of Massachusetts, Amherst, 01003, MA

来源：

POLYMER BULLETIN | 1992年 / 29卷 / 05期

关键词：

D O I：

10.1007/BF00296712

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Styrene polymerization was initiated by methylaluminoxane in the presence of haloalkane. The propagating species are shown by trapping experiments and electron paramagnetic resonance to be both radicals and cations.

引用

页码：515 / 519

页数：5

共 5 条

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CHIEN, JCW ;

SALAJKA, Z .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (09) :1243-1251

[2] SYNDIOSPECIFIC POLYMERIZATION OF STYRENE .2. MONOCYCLOPENTADIENYLTRIBUTOXY TITANIUM METHYLALUMINOXANE CATALYST [J].

CHIEN, JCW ;

SALAJKA, Z .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (09) :1253-1263

[3]

CHIEN JCW, IN PRESS MACROMOLECU

[4] STEREOSPECIFIC POLYMERIZATION OF STYRENE GIVING THE SYNDIOTACTIC POLYMER [J].

ISHIHARA, N ;

KURAMOTO, M ;

UOI, M .

MACROMOLECULES, 1988, 21 (12) :3356-3360

[5]

ISHIHARA N, 1986, MACROMOLECULES, V19, P2465

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