PERIODIC ORBIT DESCRIPTION OF TUNNELING IN SYMMETRIC AND ASYMMETRIC DOUBLE-WELL POTENTIALS

被引：133

作者：

MILLER, WH ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY LAWRENCE BERKELEY LAB,DIV MAT & MOLEC RES,BERKELEY,CA 94720

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 08期

关键词：

D O I：

10.1021/j100471a015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Semiclassical periodic orbit theory is applied to the double-well eigenvalue problem to show how this unified approach describes the quite different character of the level splitting (in the case of symmetric wells) and level shifts (in the asymmetric case) caused by tunneling. © 1979 American Chemical Society.

引用

页码：960 / 963

页数：4

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