A STERICALLY SWITCHED IONOPHORE

被引：8

作者：

RABAN, M

QUIN, J

BELGUISE, A

机构：

[1] Department of Chemistry Wayne State University Detroit

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(00)71211-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A cyclohexane pro-inophore is held in one chair form (non-ionophoric) by a large, tertiary, ketal moiety. Upon hydrolysis the acetyl group is small enough to be axial and the cyclohexane ring can flip to an ionophoric conformation.

引用

页码：35 / 38

页数：4

共 14 条

[1] BIOLOGICALLY USEFUL CHELATORS THAT TAKE UP CA-2+ UPON ILLUMINATION [J].

ADAMS, SR ;

KAO, JPY ;

TSIEN, RY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (20) :7957-7968

[2] A NEW ALLOSTERIC BIS CROWN ETHER LIGAND THAT DISPLAYS NEGATIVE BINDING CO-OPERATIVITY OF THE DIQUAT DICATION BY THE COMPLEXATION OF A TRANSITION-METAL GUEST [J].

BEER, PD ;

ROTHIN, AS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (01) :52-54

[3]

BUCHANAN GW, 1983, CAN J CHEM, V48, P888

[4]

Hirsch J. A., 1967, TOP STEREOCHEM, V3, P199, DOI [10.1002/9780470147108.ch4, DOI 10.1002/9780470147108.CH4]

[5] TRANSITION-METAL INDUCED SELECTIVE ALKALINE METAL-ION TRANSPORT BY A SYNTHETIC IONOPHORE WITH DOUBLE RECOGNITION SITES FOR METALS [J].

NABESHIMA, T ;

INABA, T ;

FURUKAWA, N .

TETRAHEDRON LETTERS, 1987, 28 (49) :6211-6214

[6]

OKAHARA M, 1985, TOP CURR CHEM, V121, P37

[7]

RABAN M, 1985, J CHEM SOC CHEM COMM, P1557

[8] 1,2-DITHIA-5,8,11,14-TETRAOXACYCLOHEXADECANE AND 1,2-DITHIA-5,8,11,14,17-PENTAOXACYCLONONADECANE - SWITCHED-ON CROWN ETHERS [J].

RABAN, M ;

GREENBLATT, J ;

KANDIL, F .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (23) :1409-1411

[9] ALLOSTERIC EFFECTS - AN ON OFF SWITCH [J].

REBEK, J ;

MARSHALL, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (22) :6668-6670

[10] ALLOSTERIC EFFECTS - REMOTE-CONTROL OF ION-TRANSPORT SELECTIVITY [J].

REBEK, J ;

WATTLEY, RV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (14) :4853-4854

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