A NEW STRUCTURE TYPE OF THE FORMULA A2MO4-PB2MNO4, A TUNNEL STRUCTURE WITH ONE-SIDED COORDINATION OF PB-2+ IONS

被引：12

作者：

TEICHERT, A ^{[1
]}

MULLERBUSCHBAUM, H ^{[1
]}

机构：

[1] UNIV KIEL,INST ANORGAN CHEM,OLSHAUSENSTR 40-60,W-2300 KIEL 1,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 598卷 / 7-8期

关键词：

DILEAD MANGANATE (IV); PREPARATION; SINGLE CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19915980129

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pb2MnO4 was prepared and investigated by single crystal X-ray technique (space group D2d4 - P42(1)cBAR; a = 12.773; c = 5.142 angstrom; Z = 8). Pb2MnO4 crystallizes with a new structure type, it is not isotypic to Pb2PbO4 or Pb2PtO4. The main difference of the new structure type concerns zig-zag-chains of edge connected MnO6-octahedra. The polyhedra network and the tunnel frame of Pb2+ are nevertheless very similar to the Pb3O4 structure.

引用

页码：319 / 325

页数：7

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