CONDUCTIVITY AND THE ELECTRIC MODULUS IN POLYMERS

被引：110

作者：

STARKWEATHER, HW

AVAKIAN, P

机构：

[1] E. I. du Pont de Nemours and Company, Central Research and Development Department, Experimental Station, Wilmington, Delaware

来源：

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 1992年 / 30卷 / 06期

关键词：

CONDUCTIVITY AND ELECTRIC MODULUS IN POLYMERS; CHAIN MOTION AND CONDUCTIVITY OF POLYMERS; NYLONS; ELECTRICAL PROPERTIES OF; POLY(BUTYLENE TERPHTHALATE); POLYCARBONATES;

D O I：

10.1002/polb.1992.090300614

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

At relatively high temperatures and low frequencies the electrical properties of many polymers are dominated by ionic conductivity. In cases where the glass transition is obscured by conductivity, it can be revealed by treating the data in terms of the electric modulus. The magnitude of the activation energy for conductivity (24-67 kcal/mol) for Nylons 6, 66, and 6I, polybutylene terephthalate, and polycarbonate indicates that the transport of charged particles requires the motion of polymer segments.

引用

页码：637 / 641

页数：5

共 12 条

[1] DIELECTRIC PROPERTIES OF POLYAMIDES - POLYHEXAMETHYLENE ADIPAMIDE AND POLYHEXAMETHYLENE SEBACAMIDE [J].

CURTIS, AJ .

JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1961, A 65 (03) :185-+

[2] THE ROLE OF BOUNDARY-LAYER CAPACITANCE AT BLOCKING ELECTRODES IN THE INTERPRETATION OF DIELECTRIC CURE DATA IN ADHESIVES [J].

DAY, DR ;

LEWIS, TJ ;

LEE, HL ;

SENTURIA, SD .

JOURNAL OF ADHESION, 1985, 18 (01) :73-90

[3]

FONTANELLA JJ, COMMUNICATION

[4] ANISOTROPY STUDY OF ELECTRICAL-CONDUCTION IN ORIENTED POLYMERS .3. THE ANISOTROPY OF ELECTRICAL-CONDUCTION IN DOUBLY-ORIENTED NYLON-12 [J].

HIROTA, S .

JOURNAL OF APPLIED PHYSICS, 1982, 53 (05) :3792-3798

[5] ANISOTROPY STUDY OF ELECTRICAL-CONDUCTION IN ORIENTED POLYMERS .2. ANISOTROPY OF ELECTRICAL-CONDUCTION IN UNIAXIALLY ORIENTED POLYMERS [J].

HIROTA, S .

JOURNAL OF APPLIED PHYSICS, 1979, 50 (05) :3007-3011

[6] ELECTRICAL CONDUCTIVITY OF NYLON 66 [J].

ISODA, S ;

MIYAJI, H ;

ASAI, K .

JAPANESE JOURNAL OF APPLIED PHYSICS, 1973, 12 (11) :1799-1805

[7]

MACEDO PB, 1972, PHYS CHEM GLASSES, V13, P171

[8]

McCrum N.G., 1967, ANELASTIC DIELECTRIC

[9]

RUSHTON E, 1956, LT355 BR EL IND RES

[10]

SEANOR DA, 1967, J POLYMER SCI C, V17, P195

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