A FACILE, HIGH-YIELD SYNTHESIS OF [PT-2(PR(3))(2)(MU-CL)(2)CL-2]

被引：16

作者：

BOAG, NM

RAVETZ, MS

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 21期

关键词：

D O I：

10.1039/dt9950003473

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Contrary to previous reports, Zeise's dimer, [Pt-2(eta(2)-C2H4)(2)(mu-Cl)(2)Cl-2], reacts with tertiary phosphines in refluxing toluene or tetrachloroethane to give high yields of the phosphine-substituted analogues [Pt-2(PR(3))(2)(mu-Cl)(2)Cl-2][PR(3) = PMe(3), PMe(2)Ph, PEt(2)Ph, P(C6H11)(2)Ph, PMePh(2), P(C6H11) Ph(2) or PPh(3)]. A wide range of examples has been synthesised and fully characterised by P-31-(H-1) and Pt-195-{1H} spectroscopy.

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页码：3473 / 3474

页数：2

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