CARBON CARBON COUPLING BETWEEN OLEFINIC C-ATOMS ON A CLUSTER AS A LEWIS ACID-BASE REACTION

被引：15

作者：

HEINEKE, D ^{[1
]}

VAHRENKAMP, H ^{[1
]}

机构：

[1] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,W-7800 FREIBURG,GERMANY

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 05期

关键词：

D O I：

10.1021/om00119a051

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The CH2 group of the nonpolar cluster compound FeCo2(CO)9(μ3-η2-C=CH2) as a Lewis acid has been attached to the methylene group of the neutral phosphorus ylides Ph3P=CHR (R = H, SiMe3, C(O)Ph, COOEt) as a Lewis base. This is the first case of a Lewis acid-base combination of two uncharged methylene units resulting in an isolable primary product. © 1990, American Chemical Society. All rights reserved.

引用

页码：1697 / 1699

页数：3

共 16 条

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