STEREOSPECIFIC TELLURIDE-MEDIATED CONVERSION OF GLYCIDOLS TO ALLYL ALCOHOLS - AN EXTENSION OF THE SHARPLESS KINETIC RESOLUTION

被引：23

作者：

DISCORDIA, RP ^{[1
]}

DITTMER, DC ^{[1
]}

机构：

[1] SYRACUSE UNIV,CTR SCI & TECHNOL,DEPT CHEM,SYRACUSE,NY 13244

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 05期

关键词：

D O I：

10.1021/jo00292a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: Treatment of methanesulfonate esters of terminal glycidols obtained by epoxidation in the Sharpless kinetic resolution (SKR) of 1-substituted 2-propenols (secondary allyl alcohols) with telluride ion (Te2-) converts the glycidols to allyl alcohols of the same stereochemical configuration as the unreacted enantiomer from the SKR. © 1990, American Chemical Society. All rights reserved.

引用

页码：1414 / 1415

页数：2

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