ALKYLATION OF (AS, SB, BI)CL3 - FORMATION OF [(AS, SB, BI)RCL2], (E)-[BIR(CH2CH=C)(SIME3)(C5H4N-2)] AND 2-CH(SIME3)2C5H4N-5-R [R = C(SIME3)2C5H4N-2]

被引：35

作者：

JONES, C

ENGELHARDT, LM

JUNK, PC

HUTCHINGS, DS

PATALINGHUG, WC

RASTON, CL

WHITE, AH

机构：

[1] GRIFFITH UNIV,DIV SCI & TECHNOL,NATHAN,QLD 4111,AUSTRALIA

[2] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6009,AUSTRALIA

[3] DELASALLE UNIV,DEPT CHEM,MANILA,PHILIPPINES

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 21期

关键词：

D O I：

10.1039/c39910001560

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Monomeric alkyldichloro-antimony(III) and -bismuth(III) compounds [MRCl2], R = C(SiMe3)2C5H4N-2', and the thermally unstable arsenic(III) analogue are accessible from the appropriate group 15 trichloride and LiR in diethyl ether; treating BiCl3 with two and three equivalents of LiR in tetrahydrofuran (THF) yields (E)-[BiR(CH2CH = C)(SiMe3)(C5H4N-2)] where the C2 insertion-SiMe3 elimination fragment originates from THF, and the 'head-to-tail' alkyl coupled species, 2-CH(SiMe3)2C5H4N-5-R.

引用

收藏

页码：1560 / 1562

页数：3

相关论文

共 17 条

[1] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A HOMOLEPTIC BISMUTH AMIDE [J].

CLEGG, W ;

COMPTON, NA ;

ERRINGTON, RJ ;

NORMAN, NC ;

WISHART, N .

POLYHEDRON, 1989, 8 (12) :1579-1580

[2] DOUBLE BONDING BETWEEN THE HEAVIER MAIN-GROUP ELEMENTS - FROM REACTIVE INTERMEDIATES TO ISOLABLE MOLECULES [J].

COWLEY, AH .

POLYHEDRON, 1984, 3 (04) :389-432

[3] THE 1ST MONOMERIC CRYSTALLINE TIN(II) ALKYLS - X-RAY STRUCTURES OF THE BETA-N-FUNCTIONALIZED ALKYLS SN(R)X [R=C(SIME3)2C5H4N-2 AND X=R, CL, OR N(SIME3)2] [J].

ENGELHARDT, LM ;

JOLLY, BS ;

LAPPERT, MF ;

RASTON, CL ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (05) :336-338

[4] ALKYLALUMINUM CATIONS - SYNTHESIS AND STRUCTURE OF [AL(2-C(SIME3)2C5H4N)2][ALCL4] [J].

ENGELHARDT, LM ;

KYNAST, U ;

RASTON, CL ;

WHITE, AH .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (07) :681-682

[5]

ENGELHARDT LM, UNPUB

[6] HEAVY-METAL PI-COMPLEXES .6. INTRAMOLECULAR AND INTERMOLECULAR ANTIMONY-CP-PI INTERACTIONS IN PHOTOSENSITIVE C5H5SBCL2 [J].

FRANK, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 406 (03) :331-341

[7] HEAVY-METAL PI-COMPLEXES .4. SYNTHESIS, PROPERTIES AND CRYSTAL-STRUCTURE OF RED C5H5BICL2 - CHAIN POLYMER WITH HAPTITATIVE DISORDER OF PI-BONDED CYCLOPENTADIENYL LIGANDS [J].

FRANK, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 386 (02) :177-186

[8]

GREENWOOD NN, 1989, CHEM ELEMENTS, P653

[9] SYNTHESES AND STRUCTURES OF HIGHLY HINDERED N-FUNCTIONALIZED ALKYL GROUP-2 METAL-COMPLEXES [M(NC5H4C(SIME3)2-2)2] (M = MG, ZN, CD, OR HG) [J].

HENDERSON, MJ ;

PAPASERGIO, RI ;

RASTON, CL ;

WHITE, AH ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (09) :672-674

[10]

HITCHINGS DS, 1989, J CHEM SOC CHEM COMM, P973