SYNTHESIS AND STRUCTURE OF FAC-TRIS[(8-QUINOLYL)DIMETHYLSILYL]RHODIUM(III) AND IRIDIUM(III)

被引：21

作者：

DJUROVICH, PI ^{[1
]}

SAFIR, AL ^{[1
]}

KEDER, NL ^{[1
]}

WATTS, RJ ^{[1
]}

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 15期

关键词：

D O I：

10.1021/ic00041a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first tris-N,Si-ligated metal complexes have been prepared in high yield by a reaction between (8-quinolyl)dimethylsilane (dmsiqn-H) and M(PPh3)3(CO)(H) (M = Rh, Ir) in refluxing toluene. The X-ray crystal structures of Rh(dmsiqn)3 and Ir(dmsiqn)3, which are isomorphous, have been determined. The molecular dipoles of the molecules in the crystal are aligned in a manner which can provide the solid with nonlinear optical properties.

引用

页码：3195 / 3196

页数：2

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