SYNTHESIS AND STRUCTURE OF FAC-TRIS[(8-QUINOLYL)DIMETHYLSILYL]RHODIUM(III) AND IRIDIUM(III)

被引:21
作者
DJUROVICH, PI [1 ]
SAFIR, AL [1 ]
KEDER, NL [1 ]
WATTS, RJ [1 ]
机构
[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106
关键词
D O I
10.1021/ic00041a006
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The first tris-N,Si-ligated metal complexes have been prepared in high yield by a reaction between (8-quinolyl)dimethylsilane (dmsiqn-H) and M(PPh3)3(CO)(H) (M = Rh, Ir) in refluxing toluene. The X-ray crystal structures of Rh(dmsiqn)3 and Ir(dmsiqn)3, which are isomorphous, have been determined. The molecular dipoles of the molecules in the crystal are aligned in a manner which can provide the solid with nonlinear optical properties.
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收藏
页码:3195 / 3196
页数:2
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