CRYSTAL-STRUCTURE AND SPECTROSCOPIC PROPERTIES OF A POLYNUCLEAR COMPLEX BETWEEN [BIS(2-AMINOETHYL)AMINE]COPPER(II) AND HEXACYANOFERRATE(III)

被引：48

作者：

MORPURGO, GO ^{[1
]}

MOSINI, V ^{[1
]}

PORTA, P ^{[1
]}

DESSY, G ^{[1
]}

FARES, V ^{[1
]}

机构：

[1] CNR, TEORIA STRUTTURA ELETTRONICA & COMPORTAMENTO SPETT, I-00131 ROME, ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1981年 / 01期

关键词：

D O I：

10.1039/dt9810000111

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of [Fe(CN)6]3- to [Cu(dien)]2+ [dien = diethylenetriamine, bis(2-aminoethyl)amine] [model for Cu-containing enzymes] gives a polynuclear complex of formula 3[Cu(dien)]2+.cntdot.2[Fe(CN)6]3-.cntdot.6H2O. The compound was characterized by IR, ESR and reflectance spectra, and its crystal and molecular structure solved by single-crystal X-ray diffractometry.

引用

页码：111 / 117

页数：7

共 27 条

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