PALLADIUM-CATALYZED DECARBOXYLATION-DEHYDROGENATION OF ALLYL BETA-KETO CARBOXYLATES AND ALLYL ENOL CARBONATES AS A NOVEL SYNTHETIC METHOD FOR ALPHA-SUBSTITUTED ALPHA,BETA-UNSATURATED KETONES

被引：109

作者：

SHIMIZU, I ^{[1
]}

TSUJI, J ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM ENGN,TOKYO 152,JAPAN

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1982年 / 104卷 / 21期

关键词：

D O I：

10.1021/ja00385a075

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：5844 / 5846

页数：3

共 9 条

[1] DEHYDRATION OF KETONES WITH PALLADIUM(II) COMPOUNDS [J].

BIERLING, B ;

SCHULZ, M ;

OBERENDE.H ;

KIRSCHKE, K .

JOURNAL FUR PRAKTISCHE CHEMIE, 1972, 314 (01) :170-&

[2] SYNTHESIS OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS BY PALLADIUM(II)-CATALYZED DEHYDROSILYLATION OF SILYL ENOL ETHERS [J].

ITO, Y ;

HIRAO, T ;

SAEGUSA, T .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (05) :1011-1013

[3] MECHANISMS OF THERMAL-DECOMPOSITION OF TRANS-DIALKYLBIS-(TERTIARY PHOSPHINE)PALLADIUM(II) AND CIS-DIALKYLBIS-(TERTIARY PHOSPHINE)PALLADIUM(II) - REDUCTIVE ELIMINATION AND TRANS TO CIS ISOMERIZATION [J].

OZAWA, F ;

ITO, T ;

NAKAMURA, Y ;

YAMAMOTO, A .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1981, 54 (06) :1868-1880

[4]

SCHELDON RA, 1972, ORG REACTIONS, V19, P279

[5] PALLADIUM-CATALYZED REARRANGEMENT OF ALLYLIC ESTERS OF ACETOACETIC ACID TO GIVE GAMMA,DELTA-UNSATURATED METHYL KETONES [J].

SHIMIZU, I ;

YAMADA, T ;

TSUJI, J .

TETRAHEDRON LETTERS, 1980, 21 (33) :3199-3202

[6] NEW METHOD FOR PREPARATION OF ALPHA,BETA-UNSATURATED CARBONYL COMPOUNDS [J].

THEISSEN, RJ .

JOURNAL OF ORGANIC CHEMISTRY, 1971, 36 (06) :752-&

[7] FACILE GENERATION OF A REACTIVE PALLADIUM(II) ENOLATE INTERMEDIATE BY THE DECARBOXYLATION OF PALLADIUM(II) BETA-KETOCARBOXYLATE AND ITS UTILIZATION IN ALLYLIC ACYLATION [J].

TSUDA, T ;

CHUJO, Y ;

NISHI, S ;

TAWARA, K ;

SAEGUSA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (20) :6381-6384

[8]

TSUJI J, 1979, TETRAHEDRON LETT, P613

[9] OXIDATIVE ADDITION OF ALLYL ACETATE TO PD(0) COMPLEXES [J].

YAMAMOTO, T ;

SAITO, O ;

YAMAMOTO, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (18) :5600-5602

← 1 →