DIRECT I-TYPE DOUBLING TRANSITIONS IN SOME AXIALLY SYMMETRIC MOLECULES

被引:33
作者
LAFFERTY, WJ
机构
[1] National Bureau of Standards, Washington
关键词
D O I
10.1016/S0022-2852(68)80048-7
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Direct l-type doubling transitions have been observed in the states ν21 inFCN, ν71 and 3ν71 in cyanoacetylene and ν8(E) in methyl cyanide. Precise values for q and the higher order term μ have been obtained for each of these vibrations. The effect of the l-type resonance between the Π and Φ levels of 3ν7 of cyanoacetylene is discussed. © 1965 Academic Press Inc.
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页码:359 / &
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