AROMATIC SUBSTITUTION OF OLEFIN .7. REACTIONS OF LOWER OLEFINS WITH BENZENE BY PALLADIUM ACETATE

被引:27
作者
DANNO, S
MORITANI, I
FUJIWARA, Y
机构
[1] Polymer Research Laboratory, Ube Industries Ltd., Chiba
[2] Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka, Machikaneyama
关键词
D O I
10.1016/S0040-4020(01)83020-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The phenylation of propylene, 1-butene, rans- and cis-butenes, and 1,3-butadiene with benzene was carried out in the presence of palladium acetate and acetic acid. It was concluded that, although the usual olefins predominantly undergo phenylation, an olefin which can easily form a π-allyl complex gives acetates as major products under the present reaction conditions. © 1969.
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页码:4809 / &
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