The potential environment about the water molecule in gypsum

被引：19

作者：

Kling, R. ^{[1
]}

Schiffer, J. ^{[1
]}

机构：

[1] Temple Univ, Commonwealth Syst Higher Educ, Dept Chem, Philadelphia, PA 19122 USA

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 02期

关键词：

D O I：

10.1016/0009-2614(69)80048-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A study of the vibrationally uncoupled stretchin g bands of HDO molecules in gypsum has revealed the absence of vibrational splittings associated with a double minimum potential for proton motion in the solid. Further more, the water molecule in CaSO4 (center dot) 2H(2)O has been shown to be considerably distorted vibrationally by its potential environment.

引用

页码：64 / 66

页数：3

共 13 条

[1] NEUTRON DIFFRACTION STUDY OF GYPSUM, CASO42H2O
ATOJI, M
RUNDLE, RE
[J]. JOURNAL OF CHEMICAL PHYSICS, 1958, 29 (06) : 1306 - 1311
[2] FREQUENCY SHIFTS FROM GAS TO CRYSTAL .1. SIH4 AND SID4
BALL, DF
MCKEAN, DC
[J]. SPECTROCHIMICA ACTA, 1962, 18 (08): : 1029 - 1037
[3] CABANNES J, 1942, J PHYS-PARIS, V8, P137
[4] CABANNES J, 1953, J CHIM PHYS PCB, V50, pC89
[5] THE INFRA-RED SPECTRUM AND CRYSTAL STRUCTURE OF GYPSUM
HASS, M
SUTHERLAND, GBBM
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1956, 236 (1207): : 427 - 445
[6] STRETCHING FREQUENCIES AS A FUNCTION OF DISTANCES IN HYDROGEN BONDS
NAKAMOTO, K
MARGOSHES, M
RUNDLE, RE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (24) : 6480 - 6486
[7] PAIN C, 1953, CR HEBD ACAD SCI, V237, P238
[8] SCHIFFER J, 1969, NBS SPECIAL PUBLICAT, V301
[9] SCHIFFER J, 1963, THESIS PRINCETON U
[10] DOUBLE-MINIMUM POTENTIALS IN HYDROGEN-BONDED SOLIDS
SOMORJAI, RL
HORNIG, DF
[J]. JOURNAL OF CHEMICAL PHYSICS, 1962, 36 (08) : 1980 - &

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