THE LOCALIZATION MODEL OF RUBBER ELASTICITY .2.

被引：53

作者：

GAYLORD, RJ ^{[1
]}

DOUGLAS, JF ^{[1
]}

机构：

[1] NATL INST STAND & TECHNOL,DIV POLYMER,GAITHERSBURG,MD 20899

来源：

POLYMER BULLETIN | 1990年 / 23卷 / 05期

关键词：

D O I：

10.1007/BF00419973

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The effect of the spatial localization of a network chain by surrounding chains is incorporated into the chain probability distribution function and the network free energy is then calculated using the statistical mechanical formalism for constrained systems. In addition to a term having the classical 'Gaussian' form, the resulting expression contains another term which depends on both the cross-link density of the network and the plateau modulus of the uncross-linked melt. © 1990 Springer-Verlag.

引用

页码：529 / 533

页数：5