ROLE OF SILICON IN POLYMER SYNTHESIS - ACTIVATION OF THE OXIDATIVE COUPLING OF THIOPHENE BY TRIMETHYLSILYL SUBSTITUENTS - A ROUTE TO HIGH-MOLECULAR-WEIGHT POLY(3-ALKYL)THIOPHENE

被引：21

作者：

BOUACHRINE, M

LEREPORTE, JP

MOREAU, JJE

MAN, MWC

机构：

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 05期

关键词：

D O I：

10.1039/jm9950500797

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The role of silyl substituents in the anodic polymerization of thiophene has been studied. The oxidative polymerization reaction is activated by the presence of trimethylsilyl groups. In order to obtain polymer of high molecular weight and low polydispersity, two such trimethylsilyl substituents in the 2,5-positions of the thiophene ring were found to be necessary,

引用

页码：797 / 799

页数：3

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