ORGANOMETALLIC ELECTROCHEMISTRY .15. ELECTRON-NUCLEAR SPIN-SPIN COUPLING INVOLVING MERCURY . ORGANOMERCURIAL RADICAL ANIONS

被引：17

作者：

DESSY, RE

KLEINER, M

COHEN, SC

机构：

[1] Department of Chemistry, Virginia Polytechnic Institute, Blacksburg

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 24期

关键词：

D O I：

10.1021/ja01052a043

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of organomercurial radical anions have been prepared, and hyperfine splitting constants for mercury, aHg, measured. It appears that a McConnell-type equation holds: a = QHgcHgpc, with QHgcHg ≅ - 200 G. © 1969, American Chemical Society. All rights reserved.

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页码：6800 / &

相关论文

共 22 条

[1] ELECTRON SPIN RESONANCE STUDIES OF RADICAL ANIONS .2. AROMATIC NITRO-COMPOUNDS [J].

AYSCOUGH, PB ;

WILSON, R ;

SARGENT, FP .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (NOV) :5418-&

[2] ORGANOMETALLIC ELECTROCHEMISTRY .2. CARBANION STABILITIES [J].

DESSY, RE ;

KITCHING, W ;

PSARRAS, T ;

SALINGER, R ;

CHEN, A ;

CHIVERS, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (03) :460-&

[3] ORGANOMETALLIC ELECTROCHEMISTRY .14. CONVERSION OF FORMAL PI ACCEPTORS TO PI DONORS [J].

DESSY, RE ;

WIECZORE.L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (18) :4963-&

[4] NUCLEAR MAGNETIC RESONANCE SPECTRA OF SOME DIALKYLMERCURY COMPOUNDS [J].

DESSY, RE ;

FLAUTT, TJ ;

JAFFE, HH ;

REYNOLDS, GF .

JOURNAL OF CHEMICAL PHYSICS, 1959, 30 (06) :1422-1425

[5] ORGANOMETALLIC ELECTROCHEMISTRY .4. TRANSITION SERIES [J].

DESSY, RE ;

STARY, FE ;

KING, RB ;

WALDROP, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (03) :471-&

[6] SOME 199HG-1H SPIN-SPIN COUPLING CONSTANTS [J].

EVANS, DF ;

RIDOUT, PM ;

WHARF, I .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (09) :2127-&

[7] THEORY OF LINEWIDTHS IN ELECTRON SPIN RESONANCE SPECTRA [J].

FREED, JH ;

FRAENKEL, GK .

JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (02) :326-+

[8]

GESKI DH, 1960, J AMER CHEM SOC, V82, P2631

[9]

GUPTA RK, 1966, J CHEM PHYS, V48, P2453

[10] ELECTRON COUPLING OF NUCLEAR SPINS .1. PROTON AND FLUORINE MAGNETIC RESONANCE SPECTRA OF SOME SUBSTITUTED BENZENES [J].

GUTOWSKY, HS ;

HOLM, CH ;

SAIKA, A ;

WILLIAMS, GA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (17) :4596-4605