KINETICS AND MECHANISM OF DECOMPOSITION OF COBALT TETRACARBONYL HYDRIDE TO DICOBALT OCTACARBONYL AND HYDROGEN

被引：72

作者：

UNGVARY, F

MARKO, L

机构：

[1] Institute of Organic Chemistry, University of Chemical Industries, Veszprém

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 20卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)80107-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The decomposition of cobalt tetracarbonyl hydride to dicobalt octacarbonyl and hydrogen in n-heptane follows the kinetic equation {A figure is presented} The rate determining step is a reaction between HCo(CO)3 and HCo(CO)4, which does not involve the cobalt-hydrogen bonds. The concentration of HCo(CO)3 in equilibrium with HCo(CO)4 can be calculated. © 1969.

引用

页码：205 / &

共 11 条

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