SYNTHESIS OF MU-ALKYLIDENE COMPLEXES OF TUNGSTEN

被引：31

作者：

LEVISALLES, J ^{[1
]}

RUDLER, H ^{[1
]}

JEANNIN, Y ^{[1
]}

DAHAN, F ^{[1
]}

机构：

[1] UNIV PARIS 06, CHIM METAUX TRANSIT LAB, EQUIPE RECH 608, F-75230 PARIS 05, FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 178卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)94234-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of EtOCMeW(CO)5 with MeLi, followed by acidification with CF3CO2H, afforded a red crystalline compound. This was found to be the bi-nuclear complex (CO)4WW(CO)4CHCHCME2 by X ray analysis and NMR spectroscopy. A mechanism for the formation of this binuclear complex is outlined. © 1979.

引用

页码：C8 / C12

页数：5

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