CRYSTAL AND ELECTRONIC-STRUCTURES OF (BEDT-TTF)2(KHG(SCN)4), (BEDT-TTF)2(NH4HG(SCN)4)

被引：270

作者：

MORI, H

TANAKA, S

OSHIMA, M

SAITO, G

MORI, T

MARUYAMA, Y

INOKUCHI, H

机构：

[1] INST SOLID STATE PHYS, MINATO KU, TOKYO 106, JAPAN

[2] INST MOLEC SCI, OKAZAKI, AICHI 444, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 08期

关键词：

Ions;

D O I：

10.1246/bcsj.63.2183

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of (BEDT-TTF)2[MHg(SCN)4] (M=K at 298 and 104 K and M=NH4 at 298 K) were determined by X-ray analyses. A donor layer and an anion sheet stack alternately along the B-axis. The packing pattern of the donor is close to α-phase, while an anion sheet constructs a thick two-dimensional polymer plane parallel to (010). The linkage of ..SC..K (or NH4) ••NCSHg-SCN in an anion sheet is very unique. The band structure calculation indicates both a closed and an open Fermi surfaces, resembling that of K-(BEDT-TTF)2[Cu(NCS)2]. © 1990 The Chemical Society of Japan.

引用

页码：2183 / 2190

页数：8

共 26 条

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