THERMOCHEMISTRY OF AZIDES .1. THE STANDARD ENTHALPY OF FORMATION OF AMMONIUM AZIDE AND OF THE AZIDE ION

被引：11

作者：

FINCH, A

GARDNER, PJ

HEAD, AJ

WU, XP

机构：

[1] Department of Chemistry, Royal Holloway and Bedford New College (University of London), Egham

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1990年 / 22卷 / 03期

关键词：

D O I：

10.1016/0021-9614(90)90203-3

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The standard (p⊖ = 0.1 MPa) molar enthalpy of formation of ammonium azide at 298.15 K has been derived from measurements of the energy of combustion in oxygen as ΔfHm⊖(cr) = (114.14±0.94) kJ·mol-1. From measurements of the molar enthalpy of solution of NH4N3(cr) in water, the value ΔfHm⊖(N3-, aq, ∞) = (274.63±0.97) kJ·mol-1 has been calculated. © 1990.

引用

页码：301 / 305

页数：5

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[2]

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[3]

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[4]

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