THERMODYNAMIC PROPERTIES OF DYF3, HOF3, ERF3, AND TMF3 - GALVANIC-CELL MEASUREMENTS USING SOLID CAF2 ELECTROLYTE

被引：17

作者：

REZUKHINA, TN

SISOEVA, TF

机构：

[1] Moscow State University, Chemical Faculty, Laboratory of Chemical Thermodynamics, Moscow

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1979年 / 11卷 / 11期

关键词：

D O I：

10.1016/0021-9614(79)90140-X

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The e.m.f.'s of the following solid-fluoride electrolyte galvanic cells have been measured over the temperature ranges shown. (1)Gd, GdF3|CaF2|DyF3, Dy (920 to 1170 K)(2)Gd, GdF3|CaF2|HoF3, Ho (1140 to 1212 K)(3)Gd, GdF3|CaF2|ErF3, ER (1145 to 1255 K)(4)Gd, GdF3|CaF2|TmF3, Tm (953 to 1080 K) Thermodynamic functions have been derived from the results for the reactions: Dy + 1.5F2 = DyF3, Ho + 1.5F2 = HoF3, Er + 1.5F2 = ErF3, and Tm + 1.5F2 = TmF3. © 1979.

引用

页码：1095 / 1099

页数：5

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