KINETICS OF THE REACTION OF CHLORINE WITH FORMIC-ACID IN AQUEOUS SULFURIC-ACID

被引:16
作者
HOQ, MF
INDU, B
ERNST, WR
NEUMANN, HM
机构
[1] GEORGIA INST TECHNOL,SCH CHEM ENGN,ATLANTA,GA 30332
[2] GEORGIA INST TECHNOL,SCH CHEM & BIOCHEM,ATLANTA,GA 30332
关键词
D O I
10.1021/j100155a034
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In sulfuric acid solution, the rate of reaction of chlorine with formic acid is proportional to formic acid and chlorine concentrations and is inversely proportional to the acidity function h}. The kinetic parameters are nearly identical with those for the reduction of bromine to bromide ions by formic acid. The two reactions a appear to follow similar mechanism-equilibrium ionization of formic acid followed by direct reaction of a formate ion with a hologen molecule.
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收藏
页码:681 / 683
页数:3
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