BIS(TRI-N-BUTYLSTANNYL)BENZOPINACOLATE - PREPARATION AND USE AS A MEDIATOR OF INTERMOLECULAR FREE-RADICAL REACTIONS

被引：18

作者：

HART, DJ

KRISHNAMURTHY, R

POOK, LM

SEELY, FL

机构：

[1] Department of Chemistry, The Ohio State University, Columbus, OH 43210

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 49期

关键词：

D O I：

10.1016/S0040-4039(00)61484-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis(tri-n-butylstannyl)benzopinacolate (2) serves as a thermal source of tri-n-butylstannyl radicals and mediates intermolecular coupling of selected alkyl halides to O-benzylformaldoxime and electron deficient olefins. A free radical non-chain mechanism is proposed for these reactions.

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收藏

页码：7819 / 7822

页数：4

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