SYNTHESIS OF 1,6-DIAMINODIAMANTANE

被引:18
作者
CHERN, YT [1 ]
WANG, JJ [1 ]
机构
[1] NATL TAIPEI COLL NURSING,TAIPEI 10764,TAIWAN
关键词
D O I
10.1016/0040-4039(95)01133-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new polycyclic diamine, 1,6-diaminodiamantane, was synthesized starting from 1,6-dibromodiamantane. The reaction of 1,6-dibromodiamantane with acetonitrile using H2SO4 as catalyst afforded 1,6-diacetamidodiamantane in 72% yield. The reaction of 1,6-diacetamidodiamantane with NaOH afforded 1,6-diaminodiamantane in 50% yield.
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页码:5805 / 5806
页数:2
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