LOW-TEMPERATURE SPECTRUM OF CO2+ IN CADMIUM DIFLUORIDE

被引：19

作者：

SIMO, C

BANKS, E

HOLT, S

机构：

[1] Chemistry Department, Polytechnic Institute of Brooklyn, Brooklyn

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 07期

关键词：

D O I：

10.1021/ic50077a015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The optical spectrum of Co2+ in CdF2 is measured at 4.2°K, Absorption bands are found centered at 3750, 4720, 7250, and 18,750 cm-1. Fine structure associated with vibrational and spin-orbit components is observed; Dq and B are obtained. Above 8 mol % (3.5 M Co2+ in CdF2) the intensity-giving mechanism is seen to change from vibronic to static distortion. © 1969, American Chemical Society. All rights reserved.

引用

页码：1446 / &

共 16 条

[1]

ABBRUSCATO VM, 1967, THESIS POLYTECHNIC I

[2] LATTICE SPECTRUM AND DIELECTRIC PROPERTIES OF EUF2 [J].