ELECTROCATALYSIS OF ANODIC OXYGEN-TRANSFER REACTIONS - FE-DOPED BETA-LEAD DIOXIDE ELECTRODEPOSITED ON NOBLE-METALS

被引:59
作者
FENG, JR
JOHNSON, DC
机构
[1] IOWA STATE UNIV SCI & TECHNOL,DEPT CHEM,AMES,IA 50011
[2] IOWA STATE UNIV SCI & TECHNOL,US DOE,AMES LAB,AMES,IA 50011
关键词
D O I
10.1149/1.2086488
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Films of Fe(III)-doped beta-PbO2 were electrodeposited from solutions containing Pb(II) and Fe(II) onto noble metal substrates. Scanning electron micrographs indicated the films consisted of a densely packed array of small crystallites. The Fe-PbO2 film electrodes were determined to be substantially more active than pure PbO2 film electrodes for several anodic oxygen-transfer reactions, including the oxidations of Mn2+ and CN−. © 1990, The Electrochemical Society, Inc. All rights reserved.
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页码:507 / 510
页数:4
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