LIQUID-CHROMATOGRAPHY MASS-SPECTROMETRY STUDIES OF 9-FLUORENYLMETHYL CHLOROFORMATE DERIVATIVES OF POLYAMINES

被引：5

作者：

LU, Z ^{[1
]}

VEENING, H ^{[1
]}

COUTANT, JE ^{[1
]}

机构：

[1] MERRELL DOW RES INST,CINCINNATI,OH 45215

来源：

JOURNAL OF CHROMATOGRAPHY | 1991年 / 540卷 / 1-2期

关键词：

D O I：

10.1016/S0021-9673(01)88809-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Liquid chromatography-mass spectrometry experiments were carried out to elucidate the structure of the carbamate derivatives formed when polyamines, such as ethylenediamine and putrescine, react with the precolumn fluorophore forming reagent, 9-fluorenylmethyl chloroformate. It has been shown that both primary amine functionalities derivatize with the reagent for polyamines.

引用

页码：199 / 206

页数：8

共 6 条

[1] HIGH-SENSITIVITY AMINO-ACID ANALYSIS BY DERIVATIZATION WITH ORTHO-PHTHALADEHYDE AND 9-FLUORENYLMETHYL CHLOROFORMATE USING FLUORESCENCE DETECTION - APPLICATIONS IN PROTEIN-STRUCTURE DETERMINATION [J].