RATE CONSTANTS FOR OZONE FORMATION AND FOR ISOTOPIC EXCHANGE-REACTIONS

被引：28

作者：

GROSS, A

BILLING, GD

机构：

[1] Department of Chemistry, H.C. Ørsted Institute, University of Copenhagen

来源：

CHEMICAL PHYSICS | 1993年 / 173卷 / 03期

关键词：

D O I：

10.1016/0301-0104(93)80155-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rate constants for the formation of ozone O2+O+M-->O3+M and the isotopic substitution reactions O-16+O-18(2)-->O-16O-18+O-18, and O-18+O-16O-18-->O-18(2)+O-16 have been calculated using two different potential energy surfaces. The calculations have been carried out using a quasiclassical trajectory method in which the classical equations of motion are solved using hyperspherical coordinates for the three-body problem. The ter-molecular rate constant for the formation of ozone has been obtained from the calculated life-times of the ozone molecules formed by the O2 + O colliSionS Using a simple collision model for the O3 + M stabilization.

引用

页码：393 / 406

页数：14

共 23 条

[1] KINETICS OF THE ISOTOPE EXCHANGE-REACTION OF O-18 WITH NO AND O-2 AT 298-K [J].