INTERACTION OF HYDROGEN WITH COPPER CHROMITE SURFACE

被引：13

作者：

KHASIN, AV

SIMENTSOVA, II

YURIEVA, TM

机构：

[1] Boreskov Institute of Catalysis, SB of RAS, Novosibirsk

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1994年 / 52卷 / 01期

关键词：

D O I：

10.1007/BF02129858

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Kinetics of the surface reduction of copper chromite, CuCr2O4, with molecular hydrogen has been studied. H-2 transformation proceeds with participation of copper reduced states, probably Cu-degrees, formed as a result of surface reaction. Process kinetics has a topochemical character. Reaction rate as a function of surface reduction degree, x, reaches a maximum near x=0.5.

引用

页码：113 / 118

页数：6

共 4 条

[1]

APAI G, 1984, APPL SURF SCI, V19, P307

[2] RELATIONSHIP BETWEEN STABLE MONO-VALENT COPPER IN COPPER CHROMIA CATALYSTS AND ACTIVITY FOR METHANOL FORMATION [J].