ELECTRON PARAMAGNETIC RESONANCE OF PU3+ IN CUBIC SYMMETRY SITES IN CAF2, SRF2, AND BAF2

被引:28
作者
EDELSTEIN, N
MOLLET, HF
EASLEY, WC
MEHLHORN, RJ
机构
[1] Lawrence Radialion Laboratory, University of California, Berkeley
关键词
D O I
10.1063/1.1672508
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The g values of the ground FT state of Pua+ in cubic symmetry sites in CaF2, SrF2, and BaF2 are 1.297± 0.001, 1.250±0.002, and 1.187±0004, respectively, as measured at r=1.2°K by EPR techniques. By fitting the g values, estimates of the crystalline-field parameters are derived. It is shown that crystallinefield effects for Pu3+ in the alkaline-earth fluorides are the same order of magnitude as in the lanthanide series.
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页码:3281 / +
页数:1
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