VIBRATIONAL ASSIGNMENTS IN BORATES WITH VATERITE STRUCTURE

被引：19

作者：

ROSS, SD

机构：

[1] Department of Chemistry, Chelsea College of Science and Technology, London, England

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1969年 / 29卷 / 02期

关键词：

D O I：

10.1016/0022-2852(69)90093-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The vibrational spectra of rare-earth borates with the vaterite structure are interpreted on the basis of a planar T-shape for the borate ion. A normal coordinate analysis of this ion is given, using a general valence force field (GVFF). The B3O9 ring with C3v symmetry is also considered as a basis for the interpretation of the infrared spectra of rare-earth borates with the vaterite structure. The frequencies for this system containing natural boron, 10B, and 11B are calculated, using a GVFF potential function. © 1969.

引用

页码：131 / &

共 24 条

[1]

BARTRAM F, 1962, RARE EARTH RES, V2, P330

[2] THE CRYSTAL STRUCTURE OF THE ISOMORPHOUS ORTHOBORATES OF COBALT AND MAGNESIUM [J].