NEAR-INFRARED ABSORPTION AND CIRCULAR DICHROISM SPECTRA OF FERROCYTOCHROME C-D-]D TRANSITIONS

被引：48

作者：

EATON, WA

CHARNEY, E

机构：

[1] Laboratory of Physical Biology, National Institute of Arthritis and Metabolic Diseases, National Institutes of Health, Bethesda

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 10期

关键词：

D O I：

10.1063/1.1671818

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transitions to the lowest crystal field singlet states of horse heart ferrocytochrome c have been identified from absorption and circular dichroism spectra in the wavelength region 5700-10 000 Å. The results are correlated with crystal field and molecular orbital theoretical predictions. The Dq value for the porphyrin ring of ferrocytochrome c is found to be between 1700 and 1900 cm-1, in excellent agreement with the extended Hückel calculations of Zerner, Gouterman, and Kobayashi.

引用

页码：4502 / &

共 29 条

[1] ON THE DICHROISM OF CERTAIN CO(III) COMPLEXES
BALLHAUSEN, CJ
MOFFITT, W
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1956, 3 (3-4): : 178 - 181
[2] BALLHAUSEN CJ, 1962, INTRODUCTION LIGAND
[3] Theories of optical rotatory power
Condon, EU
[J]. REVIEWS OF MODERN PHYSICS, 1937, 9 (04) : 0432 - 0457
[4] DICKERSON RE, 1967, J BIOL CHEM, V242, P3015
[5] DUFFIELD JJ, 1968 PITTSB C AN CHE
[6] ELECTRONIC SPECTRUM OF SINGLE CRYSTALS OF FERRICYTOCHROME-C
EATON, WA
HOCHSTRASSER, RM
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (07) : 2533 - +
[7] SINGLE-CRYSTAL SPECTRA OF FERRIMYOGLOBIN COMPLEXES IN POLARIZED LIGHT
EATON, WA
HOCHSTRASSER, RM
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (03) : 985 - +
[8] EATON WA, UNPUBLISHED RESULTS
[9] EATON WA, 1966, CHEMISTRY HEMES HEMO, P581
[10] EYRING H, 1944, OUANTUM CHEMISTRY, P17

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