APPLICATION OF XE-129 NUCLEAR-MAGNETIC-RESONANCE TO THE STUDY OF CU-Y ZEOLITES - DEHYDRATION AND REDOX EFFECTS

被引：13

作者：

GEDEON, A

BONARDET, JL

LEPETIT, C

FRAISSARD, J

机构：

[1] UNIV PARIS 06, CHIM SURFACES LAB, CNRS, URA 1428, F-75252 PARIS 05, FRANCE

[2] UNIV PARIS 06, REACT SURFACE LAB, CNRS, URA 1106, F-75252 PARIS 05, FRANCE

来源：

SOLID STATE NUCLEAR MAGNETIC RESONANCE | 1995年 / 5卷 / 02期

关键词：

XE-129 NUCLEAR MAGNETIC RESONANCE; ELECTRON SPIN RESONANCE; ZEOLITES; COPPER IONS; ION EXCHANGE;

D O I：

10.1016/0926-2040(95)00032-L

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Copper-exchanged sodium Y zeolites have been studied by using Xe-129 nuclear magnetic resonance (NMR) spectroscopy. The oxidation state as well as the location of copper in the zeolite have been determined for different samples at various levels of exchange (lambda = 15, 35, 58%) and hydration, and at different stages of redox treatment. Information about the nature of Xe-Cu+ or Xe-Cu2+ interactions has been obtained by a combination of electron spin resonance (ESR) and Xe-129 NMR measurements on Cu-Y and Cu-Rho zeolites.

引用

页码：201 / 212

页数：12

共 39 条

[1] ELECTRON-SPIN-RESONANCE AND ELECTRON-SPIN ECHO STUDY OF CU-2+ IN ZEOLITES H-RHO AND CSH-RHO [J].