REACTIONS OF PHOSPHINES WITH ACETYLENES .8. SYNTHESIS OF 1,2-DIDEUTERIATED OLEFINS

被引：38

作者：

RICHARDS, EM

TEBBY, JC

WARD, RS

WILLIAMS, DH

机构：

[1] North Staffordshire College of Technology, Stoke-on-Trent

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 11期

关键词：

D O I：

10.1039/j39690001542

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 1,2-dideuteriated olefins dimethyl[2H2]fumarate, [2H2]benzylidene acetophenone, and methyl [ 2H2]cinnamate have been prepared by a simple and economical method from disubstituted acetylenes by use of triphenyl-phosphine and deuterium oxide. The method is limited to substituents which activate the reacting acetylenic bonds towards nucleophilic attack by triphenylphosphine.

引用

页码：1542 / &

共 20 条

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