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HYDROCARBON METAL SULPHIDE COMPLEXES .3. STEREOCHEMISTRY OF SOME RHODIUM DERIVATIVES

被引：47
作者：
BOLTON, ES
HAVLIN, R
KNOX, GR
机构：
[1] Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 18卷 / 01期
关键词：
D O I：
10.1016/S0022-328X(00)80243-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The preparations of [RSRh(CO)2]2 (R = CH3, C6H5, p-FC6H4, C6F5) are reported, and their stereochemistry investigated. Rapid cleavage of the thio bridge by triphenylphosphine leads to complexes of the type cis-RSRh(CO) (PPh3)2. The slow isomerisation of these to the trans-isomer can be followed spectrometrically. © 1969.
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页码：153 / &
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