STEREOCHEMISTRY OF HYDROGENATION ON HOMOGENEOUS PHASE OF BICYCLIC METHYLENIC OLEFINS CATALYZED BY TRIS(TRIPHENYLPHOSPHINE)HALOGENRHODIUM

被引：14

作者：

ROUSSEAU, C

EVRARD, M

PETIT, F

机构：

[1] Laboratoire de Chimie Organique Appliquée, ERA CNRS no 070458, ENSCL, 59650 Villeneuve D'Ascq

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1979年 / 5卷 / 03期

关键词：

D O I：

10.1016/0304-5102(79)80054-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The stereochemistry of the reduction of 2-methylene bicyclo [2.2.1]- heptanes, more or less methylated, catalyzed by Rh(Pφ3)3X depends mainly on the substitution reaction {A figure is presented} leading to the formation of two (π-olefin)-metal complexes, precursors of endo-and exo- 2-methyl bicyclo[2.2.1] heptanes. Identical results were obtained when the same hydrogenations were carried out using a solid catalyst such as PtO2. © 1979.

引用

页码：163 / 173

页数：11

共 14 条

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