SELECTIVE ALKYLATION OF ETHYL 3-OXOGLUTARATE .2. SYNTHESIS OF A PROSTAGLANDIN INTERMEDIATE AND SYNTHESIS OF DIHYDROJASMONE AND METHYL DIHYDROJASMONATE

被引：11

作者：

NAOSHIMA, Y

MIZOBUCHI, S

WAKABAYASHI, S

机构：

[1] Department of Chemistry, Okayama University of Science, Okayama, 700, l-l Ridai-cho

来源：

AGRICULTURAL AND BIOLOGICAL CHEMISTRY | 1979年 / 43卷 / 08期

关键词：

D O I：

10.1080/00021369.1979.10863682

中图分类号：

S3 [农学（农艺学）];

学科分类号：

0901 ;

摘要：

The synthesis of 2-(6-methoxycarbonyIhexyl)cyclopent-2-ene-l-one (5), a valuable intermediate in the synthesis of prostaglandins, is described starting from ethyl 3-oxoglutarate (1). The same reaction sequence also produces dihydrojasmone (12) and methyl dihydrojas- monate (13). © 1979 Taylor & Francis Group, LLC.

引用

页码：1765 / 1768

页数：4

共 14 条

[1] STUDIES IN PROSTAGLANDINS .9. SYNTHESIS OF (+1-)-PROSTAGLANDIN-E1, (+1-)-11-DEOZYPROSTAGLANDINS-E1, F1ALPHA, AND F1BETA, AND (+1-)-9-OXO-13-CIS-PROSTENOIC ACID BY CONJUGATE ADDITION OF VINYLCOPPER REAGENTS [J].