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INVESTIGATION OF SULFUR MOLECULAR PARAMAGNETIC CENTERS IN SRCL2

被引：5
作者：
DESIEBENTHAL, JM
BILL, H
机构：
[1] Department of Physical Chemistry, University of Geneva
来源：
PHYSICA STATUS SOLIDI B-BASIC RESEARCH | 1979年 / 91卷 / 02期
关键词：
D O I：
10.1002/pssb.2220910213
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
S 2− and S 3− centers in SrCl2 single crystals are observed. The underlying experimental investigation is carried out by EPR, Raman, and optical absorption spectroscopy. The S 3− centers show dynamical features in their EPR spectra. The temperature dependence of these spectra is compared with the results of the Kubo line shape theory. This enables to identify the motion as a thermally activated reorientation of the center between two equivalent equilibrium positions. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA
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页码：479 / 486
页数：8
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