PLATINUM-COMPLEX-CATALYZED 1,4-DISILYLATION OF 1,3-DIENES USING ORGANODISILANES - REMARKABLE EFFECT OF A PHENYL FUNCTIONALITY ON A SILICON ATOM

被引：60

作者：

TSUJI, Y

LAGO, RM

TOMOHIRO, S

TSUNEISHI, H

机构：

[1] Department of Chemistry, Faculty of Engineering, Gifu University

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 07期

关键词：

D O I：

10.1021/om00043a015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Organodisilanes having a phenyl functionality on the silicon atom smoothly react with 1,3-dienes at 130-degrees-C to afford the corresponding 1,4-disilylation adducts in high yields in the presence of platinum catalyst. However, other substituents such as Me, n-Bu, t-Bu, CH2C6H5, CH2CH=CH2, and CH=CH2 on the silicon atom are totally ineffective.

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页码：2353 / 2355

页数：3

相关论文

共 39 条

[1] THERMOCHEMISTRY OF ARENE CHROMIUM TRICARBONYLS AND STRENGTHS OF ARENE-CHROMIUM BONDS [J].

ADEDEJI, FA ;

BROWN, DLS ;

CONNOR, JA ;

LEUNG, ML ;

PAZANDRADE, IM ;

SKINNER, HA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 97 (02) :221-228

[2] PREPARATION AND STRUCTURE OF 2 BINUCLEAR SANDWICH BENZENE-METAL COMPLEXES OF PALLADIUM [J].

ALLEGRA, G ;

TETTAMAN.G ;

IMMIRZI, A ;

PORRI, L ;

VITULLI, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (02) :289-&

[3]

[Anonymous], 1977, INORG CHEM, V16, P884

[4]

Bassindale A. R., 1989, CHEM ORGANIC SILIC 2, P893

[5] SYNTHESIS AND CRYSTAL-STRUCTURE OF BIS(TRIETHYLPHOSPHINE)[HEXAKIS-(TRIFLUOROMETHYL)BENZENE]PLATINUM, AND OF A NICKELACYCLOHEPTATRIENE COMPLEX [J].

BROWNING, J ;

GREEN, M ;

PENFOLD, BR ;

SPENCER, JL ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1973, (02) :31-32

[6] RING-INSERTION AND RING-OPENING REACTIONS OF OCTAETHYLCYCLOTETRASILANE [J].

CARLSON, CW ;

WEST, R .

ORGANOMETALLICS, 1983, 2 (12) :1801-1807

[7] TRI-NUCLEAR CLUSTER COMPOUNDS AND TETRA-NUCLEAR CLUSTER COMPOUNDS OF PLATINUM(O), WHICH CONTAIN TERTIARY PHOSPHINES AND CARBON MONOXIDE [J].

CHATT, J ;

CHINI, P .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (09) :1538-&

[8] IMPROVED SYNTHESIS OF MONONUCLEAR PLATINUM(O) COMPOUNDS WHICH CONTAIN TERTIARY PHOSPHINES AND CARBON MONOXIDE [J].

CHINI, P ;

LONGONI, G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (09) :1542-&

[9]

COLLMAN JP, 1987, PRINCIPLES APPLICATI, P158

[10]

Colvin E. W., 1988, SILICON REAGENTS ORG, P25

← 1 2 3 4 →