PROPAGATION FAILURE IN ARRAYS OF COUPLED BISTABLE CHEMICAL REACTORS

被引:131
作者
LAPLANTE, JP
ERNEUX, T
机构
[1] NORTHWESTERN UNIV, DEPT ENGN SCI & APPL MATH, EVANSTON, IL 60208 USA
[2] ROYAL MIL COLL CANADA, DEPT CHEM & CHEM ENGN, KINGSTON K7K 5L0, ONTARIO, CANADA
关键词
D O I
10.1021/j100191a038
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We consider a one-dimensional array of coupled stirred tank reactors. Each reactor operates with the bistable chlorite-iodide reaction. The reaction admits two stable steady states (A and B). At time zero, all reactors are at steady state A except the first reactor which is at steady state B. Provided the coupling (exchange rate) between each reactor is sufficiently large, a propagating wave joining A to B is initiated. We determine the speed of the front and show that it fails to propagate if the exchange rate is below a nonzero value. In addition, we investigate the time history of the front and identify three distinct stages. First, we note a small time regime dominated by a diffusion mechanism; second, we note a front propagating with almost constant speed; third, we note a boundary layer regime corresponding to the end of the front and the approach to the final uniform steady state. We explain all three stages by analyzing a simple model.
引用
收藏
页码:4931 / 4934
页数:4
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